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Journal Articles

Thinning behavior of solid boron carbide immersed in molten stainless steel for core disruptive accident of sodium-cooled fast reactor

Emura, Yuki; Takai, Toshihide; Kikuchi, Shin; Kamiyama, Kenji; Yamano, Hidemasa; Yokoyama, Hiroki*; Sakamoto, Kan*

Journal of Nuclear Science and Technology, 10 Pages, 2023/00

 Times Cited Count:0 Percentile:0.01(Nuclear Science & Technology)

Journal Articles

Effect of B$$_{4}$$C absorber material on melt progression and chemical forms of iodine or cesium under severe accident conditions

Hidaka, Akihide

Insights Concerning the Fukushima Daiichi Nuclear Accident, Vol.4; Endeavors by Scientists, p.341 - 356, 2021/10

Journal Articles

Modeling of eutectic reaction between molten stainless steel and B$$_{4}$$C for severe accident simulations

Liu, X.*; Morita, Koji*; Yamano, Hidemasa

Proceedings of 12th International Topical Meeting on Nuclear Reactor Thermal-Hydraulics, Operation and Safety (NUTHOS-12) (USB Flash Drive), 12 Pages, 2018/10

On the basis of experimental results, growth of the eutectic material is modeled by the parabolic rate law. Heat and mass transfer processes are also modeled considering both the equilibrium and non-equilibrium phase changes of eutectic material. Thermophysical properties of eutectic material obtained from the experimental measurements are also included in the analytic thermophysical property model and analytic equation-of-state model.

Journal Articles

Thermophysical properties of stainless steel containing 5mass%-B$$_{4}$$C in the solid phase

Takai, Toshihide; Furukawa, Tomohiro; Yamano, Hidemasa

Proceedings of 2018 International Congress on Advances in Nuclear Power Plants (ICAPP 2018) (CD-ROM), p.1007 - 1013, 2018/04

Journal Articles

Basic visualization experiments on eutectic reaction between boron carbide and stainless steel under sodium-cooled fast reactor conditions

Yamano, Hidemasa; Suzuki, Toru; Kamiyama, Kenji; Kudo, Isamu*

Proceedings of International Conference on Fast Reactors and Related Fuel Cycles; Next Generation Nuclear Systems for Sustainable Development (FR-17) (USB Flash Drive), 11 Pages, 2017/06

This paper describes basic visualization experiments on eutectic reaction and relocation of boron carbide (B$$_{4}$$C) and stainless steel (SS) under a high temperature condition exceeding 1500$$^{circ}$$C as well as the importance of such behaviors in molten core during a core disruptive accident in a Generation-IV sodium-cooled fast reactor (750 MWe class) designed in Japan. At first, a reactivity history was calculated using an exact perturbation calculation tool taking into account expected behaviors. This calculation indicated the importance of a relocation behavior of the B$$_{4}$$C-SS eutectic because its behavior has a large uncertainty in the reactivity history. To clarify this behavior, basic experiments were carried out by visualizing the reaction of a B$$_{4}$$C pellet contacted with molten SS in a high temperature-heating furnace. The experiments have shown the eutectic reaction visualization as well as freezing and relocation of the B$$_{4}$$C-SS eutectic in upper part of the solidified test piece due to the density separation.

Journal Articles

Effect of B$$_{4}$$C absorber material on melt progression and chemical forms of iodine or cesium under severe accident conditions

Hidaka, Akihide

Nihon Genshiryoku Gakkai Wabun Rombunshi, 14(1), p.51 - 61, 2015/03

B$$_{4}$$C used mainly for BWR and EPR absorbers could cause phenomena which never happen in PWR with Ag-In-Cd absorbers during severe accident. B$$_{4}$$C would make a eutectic interaction with stainless steel and enhance melt relocation. Boron oxidation could increase H$$_{2}$$ generation and change of liberated carbon to CH$$_{4}$$ could enhance CH$$_{3}$$I generation. HBO$$_{2}$$ generated during B$$_{4}$$C oxidation could be changed to CsBO$$_{2}$$ by combining with Cs. This may increase Cs deposition in reactor coolant system. There could be differences in configuration, surface area, stainless steel-B$$_{4}$$C weight ratio between B$$_{4}$$C powder and pellet absorbers. Present issue is to clarify effect of these differences on full scale melt progression, B$$_{4}$$C oxidation and source term. Advancement of this research domain could contribute to further sophistication of prediction tool for melt progression and source terms, and treatment of organic iodide formation in safety evaluation.

Journal Articles

Electrode reaction of the Np$$^{3+}$$/Np couple at liquid Cd and Bi electrodes in LiCl-KCl eutectic melts

Shirai, Osamu; Uozumi, Koichi*; Iwai, Takashi; Arai, Yasuo

Journal of Applied Electrochemistry, 34(3), p.323 - 330, 2004/03

 Times Cited Count:28 Percentile:52.41(Electrochemistry)

The electrode reactions of the Np$$^{3+}$$/Np couple at liquid Cd and Bi electrodes were investigated by cyclic voltammetry at 723, 773 and 823 K in LiCl-KCl eutectic melt. It was found that the diffusion of Np$$^{3+}$$ in the salt phase was a rate-determining step in the cathodic reaction when the concentration of NpCl$$_{3}$$ was less than about 1 wt.% and the liquid Cd or Bi phase was not saturated with Np. The redox potentials of the Np$$^{3+}$$/Np couple at liquid Cd electrode at 723, 773 and 823 K were observed more positively than those at Mo electrode by 0.158, 0.140 and 0.126 V, respectively. The potential shift would result from a lowering of activity of Np in Cd phase according to the alloy formation of NpCd$$_{11}$$ at 723 K and NpCd$$_{6}$$ at 773 and 823 K. The redox potentials of the Np$$^{3+}$$/Np couple at liquid Bi electrode at 723, 773 and 823 K were more positive than those at Mo electrode by 0.427, 0.419 and 0.410 V, respectively, which would be attributable to a lowering of activity of Np in Bi phase according to the formation of NpBi$$_{2}$$.

JAEA Reports

High temperature interaction between zircaloy-4 and stainless steel type 304

Nagase, Fumihisa; Otomo, Takashi; Uetsuka, Hiroshi

JAERI-Research 2001-009, 21 Pages, 2001/03

JAERI-Research-2001-009.pdf:2.93MB

no abstracts in English

Journal Articles

High temperature interaction between zircaloy-4 and inconel-718

Uetsuka, Hiroshi; Nagase, Fumihisa;

Journal of Nuclear Materials, 246(2-3), p.180 - 188, 1997/00

 Times Cited Count:13 Percentile:70.37(Materials Science, Multidisciplinary)

no abstracts in English

Journal Articles

Chemical interactions between B$$_{4}$$C and stainless steel at high temperatures

Nagase, Fumihisa; Uetsuka, Hiroshi;

Journal of Nuclear Materials, 245(1), p.52 - 59, 1997/00

 Times Cited Count:45 Percentile:93.53(Materials Science, Multidisciplinary)

no abstracts in English

JAEA Reports

Elemental analysis on reaction layers formed in the core materials interaction at high temperatures

Nagase, Fumihisa; Uetsuka, Hiroshi;

JAERI-Research 95-085, 48 Pages, 1995/11

JAERI-Research-95-085.pdf:2.67MB

no abstracts in English

JAEA Reports

Interaction between zircaloy tube and inconel spacer grid at high temperatures

Nagase, Fumihisa; ; Uetsuka, Hiroshi; Furuta, Teruo

JAERI-M 90-165, 35 Pages, 1990/09

JAERI-M-90-165.pdf:3.39MB

no abstracts in English

JAEA Reports

Oral presentation

Basic visualization experiments on eutectic reaction of boron carbide and stainless steel under sodium-cooled fast reactor conditions

Yamano, Hidemasa; Suzuki, Toru; Kamiyama, Kenji; Kudo, Isamu*

no journal, , 

This paper describes basic visualization experiments on eutectic reaction and relocation of boron carbide (B$$_{4}$$C) and stainless steel (SS) under a high temperature condition exceeding 1500$$^{circ}$$C as well as the importance of such behaviors in molten core during a core disruptive accident in a Generation-IV sodium-cooled fast reactor (750 MWe class) designed in Japan. At first, a reactivity history was calculated using an exact perturbation calculation tool taking into account expected behaviors. This calculation indicated the importance of a relocation behavior of the B$$_{4}$$C-SS eutectic because its behavior has a large uncertainty in the reactivity history. To clarify this behavior, basic experiments were carried out by visualizing the reaction of a B$$_{4}$$C pellet contacted with molten SS in a high temperature-heating furnace. The experiments have shown the eutectic reaction visualization as well as freezing and relocation of the B$$_{4}$$C-SS eutectic in upper part of the solidified test piece due to the density separation.

14 (Records 1-14 displayed on this page)
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